Chlorine Demand
Chlorine
Demand is a pool water chemistry topic that is getting more attention due to
changing climates, consumer's water chemistry and understanding of the
problem. It is also becoming a greater issue in many private &
commercial pools.Chlorine
Demand is defined as "the quantity of chlorine reduced or converted to
inert or less active forms of chlorine by substances in the water." Faust
and Aly's Chemistry of Water Treatment further state that, "since
chlorine is a non-selective oxidant, almost any substance in the water...will
react and consume chlorine." In other words, the more
"stuff" dissolved in the pool water, whether organic or inorganic; chemical, vegetable or mineral;
heavy, constant rainfall can cause a chlorine demand. Or more simply
stated, not being able to successfully maintain a chlorine residual following a
chock treatment. Certain household
cleaners that are not specifically formulated for in-pool-water use will add
components such as phosphates or nitrates will interfere with the pool's
sanitizer causing a chlorine demand.
Another
cause that may prove suspect, at least in our line of thinking, is the
Chloramine issue. As you
remember, chloramines are chlorine molecules that are chemically linked up (we
call them contaminated) with organic waste such as nitrogen, ammonia, etc.
More & more local water treatment authorities are using chloramines to
sanitize the
drinking water supply these days. Chloramines are pretty effective in
killing pathogens in the drinking water supply. However, chloramines are
not effective oxidizers. You've probably noticed a regular pink line in your
home sink, shower or toilet bowl, especially over the past 4 to 5 years.
Those spots need more regular cleaning. That's the same pink slime that is
in your swimming pool! Chloramines are used because they are pretty
effective and less "offensive" to those who want to rid our planet of chlorine.
That premise is utter foolishness since you can't ban or get rid of an element!
Anyway, as you top off your pool with the garden hose, you're putting more
chloramines into your pool every time and aggravating an already serious
problem. Please keep in mind that this issue is NOT pertinent to folks
with well water (you have your own issues).
Click here for further information on
chloramines.
Since 1992,
BioGuard's Technical Services Department has gathered a huge amount of data
concerning chlorine demand. It appears that the situation has become more
widespread each year. Here are some actions (short version) that can help in dealing with
Chlorine Demand.
-
Doing a proper Chlorine Demand
Test. Your local BioGuard®
Insignia Dealer should have a Chlorine Demand test station. When
determining the ACTUAL Chlorine Demand, it is imperative that the solution
& corrective action be accurate. Liken it to jumping across the
Grand Canyon, if you miss, you miss! If it takes 20 lbs of Shock to
break the chlorine demand, using 19 lbs will make the problem worse; 20 lbs
or more of Shock will treat the issue.
-
Maintenance of an adequate
sanitizer being added to the swimming pool on a daily basis. Be sure to have
the correct number of chlorine sticks or tablets dissolving into the
pool. Check this as often as daily by visually examining the chlorine
to see that it is eroding (whether in the skimmer or in a chlorinator) at a
"normal" rate. Normal refers to what you have
"normally" experienced in the past. Cool water, slower
erosion/dissolution rate; warmer water, faster erosion/dissolution rate.
-
The Pool MUST BE SHOCKED EVERY
WEEK. PERIOD. Shocking oxidizes much of the "stuff" that was
mentioned earlier.
-
If you are using a solar
blanket, REMOVE IT! After ANY
chemical addition, the chemical reaction must have time to GAS-OFF in order
to achieve the proper results.
Click here to learn more about
treating a chlorine demand.
Although a singular cause for
Chlorine Demand has not been determined (there are many), we have found a common
thread in many of these cases. One common thread is if a pool is kept
closed longer in the spring (covered without a sanitizer). Heavy rainfall
that has ammonia present will cause a Chlorine Demand. Accidental addition
of household fertilizers or any compound that can be oxidized by chlorine will
result in a Chlorine Demand.
In conclusion, Chlorine Demand needs
our attention. Only careful monitoring and quick treatment may be
successful for a clear pool. PLEASE VISIT YOUR LOCAL BIOGUARD INSIGNIA
DEALER REGULARLY (4 times per season).
Par Pool & Spa can perform a
Chlorine Demand test for you.
If you don't have a local
BioGuard Dealer with a Chlorine Demand Test Station, you may OVERNIGHT a
sample to us for testing & analysis. We will perform a complete BioGuard
Test using AccuScan and the AccuDemand 30 test stations and will provide you
with BioGuard Alex results as well as some of our own recommendations.
Please
fill out this form
(new window will open), print it, and include it with your ONE QUART water
sample (must be sent in a clean, plastic bottle that was NOT used to hold
cleaning fluids, soda, food in general - an empty water bottle is best). Please
note that there is a $15.00 charge for this testing & analysis service. A
portion of the fee ($10.00) may be applied to future chemical sales. We will
contact you by telephone with the results & recommendations.
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